Read e-book online Colloid Stability: The Role of Surface Forces - Part II, PDF

By Tharwat F. Tadros

ISBN-10: 3527315039

ISBN-13: 9783527315031

ISBN-10: 3527631097

ISBN-13: 9783527631094

The 1st smooth method of relate basic study to the utilized technological know-how of colloids, this sequence bridges educational examine and useful purposes, hence delivering the knowledge very important to either. Written via the very most sensible scientists of their respective disciplines, this quantity discusses the character of assorted forces, in addition to the effect of floor forces at the balance of dispersions, their size and function in adsorbed polymers and liquid films.
For floor, polymer and physicochemists, fabrics scientists, and chemical engineers.Content:
Chapter 1 Wetting of Surfaces and Interfaces: A Conceptual Equilibrium Thermodynamic technique (pages 1–83): Jarl B. Rosenholm
Chapter 2 floor Forces and Wetting Phenomena (pages 85–108): Victor M. Starov
Chapter three research of Plateau Border Profile form with move of Surfactant answer via Foam less than consistent strain Drop utilizing the FPDT approach (pages 109–125): Pyotr M. Kruglyakov and Natalia G. Vilkova
Chapter four actual Chemistry of Wetting Phenomena (pages 127–152): Nicolay V. Churaev and Vladimir D. Sobolev
Chapter five The Intrinsic cost on the Hydrophobe/Water Interface (pages 153–164): James okay. Beattie
Chapter 6 floor Forces in Wetting Phenomena in Fluid platforms (pages 165–182): Hiroki Matsubara and Makoto Aratono
Chapter 7 Aggregation of Microgel debris (pages 183–202): Brian Vincent and Brian Saunders
Chapter eight growth in Structural Transformation in Lyotropic Liquid Crystals (pages 203–245): Idit Amar?Yuli and Nissim Garti
Chapter nine Particle Deposition as a device for learning Hetero?Interactions (pages 247–311): Zbigniew Adamczyk, Katarzyna Jaszczolt, Aneta Michna, Maria Zembala and Jakub Barbasz
Chapter 10 fresh advancements in Dilational Viscoelasticity of Surfactant Layers (pages 313–344): Libero Liggieri, Michele Ferrari and Francesca Ravera
Chapter eleven quick Brownian and Gravitational Coagulation (pages 345–378): Andrei S. Dukhin and Stanislav S. Dukhin

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Additional info for Colloid Stability: The Role of Surface Forces - Part II, Volume 2

Example text

3 Wetting in Idealized Binary Systems Fig. 3 Zisman plot for silanized hydrophobic silica (spheres) and neat hydrophilic silica (triangles). The probe liquids are in increasing order of the surface tension; octane, hexa-decane, a-bromonaphthalene, ethylene glycol, diiodomethane, formamide and water. The contact angles have been determined in air using the Laplace approach (data partially from [8, 42]). It is seen that octane represents the critical liquid (ccrit) for the hydrophobic silica, but its surface tension is too small for the determination of the surface tension of hydrophilic silica.

Hexadecane may be considered to represent the critical liquid for the hydrophilic silica. On the other hand, water seems to have a too high surface tension in order to comply with the trend of the other probe liquids on hydrophobic silica. It thus appears that there exist a frame within the surface tensions and the surface energies are sufficiently close in order to provide physically relevant information. Outside this range the results extracted may be seriously distorted. Instead of using the total surface tension, Fowkes subtracted a dispersive part and evaluated the excess as the surface pressure of a vapor film [9].

9 plotted as a function of the surface tension of the probe liquids (for details see text and [42]). 27 28 1 Wetting of Surfaces and Interfaces: a Conceptual Equilibrium Thermodynamic Approach ponent, but the second smallest base dominance. Ethylene glycol seems to have the overall most favorable properties. With reference to the Girifalco–Good quotient it is expected that the arithmetic/total work of adhesion should not be too different from the geometric work of adhesion (U & 1). The partial contributions should then add up to the total values.

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Colloid Stability: The Role of Surface Forces - Part II, Volume 2 by Tharwat F. Tadros

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