By Henning Hopf
The 2 easy development devices carbon and hydrogen should be mixed in 1000000 alternative ways to offer a plethora of attention-grabbing natural compounds. Henning Hopf offers not just the main amazing buildings and houses of hydrocarbon compounds yet indicates in a transparent presentation and with nice didactic ability how molecules like dodecahedrane, superphane or annulenes problem the artificial talents of each natural chemist. To make the knowledge extra available, particularly to the beginner, the writer conscientiously analyzes the substitute challenge, explains every one man made step and offers tricks on substitute tools and power pitfalls. quite a few references to beneficial experiences and the unique literature make this e-book an critical resource of additional info. designated emphasis is put on the skillful use of images and schemes: artificial (retro)analyses, response sequences, and the most important steps are awarded in blue boxed sections in the textual content. Graduate scholars and researchers alike will locate this e-book a gold mine of precious details crucial for his or her day-by-day paintings. each natural chemist may want to have a duplicate on his or her table. With a foreword by way of W. von Eggers Doering.
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Extra resources for Carbon-Rich Compounds - From Molecules to Materials
Molecular dyads found to exhibit a switch in electron-transfer mechanism. tenuation factor that measures the resistivity of the bridge being b ¼ 0:57 A˚À1 for 101 and 102 . For longer bridges, an abrupt change in mechanism occurred and the rate of electron transfer was found to be less aﬀected by incremental increases in separation distance [80, 81] with b ¼ 0:04 A˚À1 for 103 and 105 . This eﬀect was explained in terms of the decrease in energy of the bridging LUMO with increased p-electron conjugation.
Nenitzescu, M. Avram, I. G. Dinulescu, G. Mateescu, Liebigs Ann. 1962, 653, 79–85. J. v. Braun, E. Anton, Ber. Dtsch. Chem. Ges. 1929, 62, 145–151. (a) N. Campbell, D. H. Reid, J. Chem. Soc. 1952, 3281–3284; (b) H. W. D. Stubbs, S. H. Tucker, J. Chem. Soc. 1951, 2936–2939. (a) V. Boekelheide, W. E. -T. Liu, J. Am. Chem. Soc. 1951, 73, 2432–2435; (b) V. Boekelheide, G. K. Vick, J. Am Chem. Soc. 1956, 78, 653–658. D. H. Reid, W. H. Stafford, J. P. Ward, J. Chem. Soc. 1955, 1193– 1201. (a) N. Campbell, H.
Soc. 1967, 89, 3069–3071; 1969, 91, 6391–6397. (a) H. Prinzbach, W. Rosswog, Angew. Chem. 1961, 73, 543; Tetrahedron Lett. 1963, 1217–1221; (b) M. Neuenschwander, W. K. Schenk, Chimia 1972, 26, 194–197. W. E. Barth, R. G. Lawton, J. Am. Chem. Soc. 1966, 88, 380–381; 1971, 93, 1730–1745. ) of electronic circuitry and integrated circuits. In many cases, the devices are simply molecularbased analogs of conventional silicon-based circuitry. Such molecular-scale systems have the great advantage, however, of less manufacturing complexity, lower power consumption and easier scaling.
Carbon-Rich Compounds - From Molecules to Materials by Henning Hopf