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Extra resources for Biopolymers / 1
Glass JE, Swift G (eds) (1990) Agricultural and synthetic polymers: biodegradability and utilization. American Chemical Society, Washington, DC 21. Huang SJ (1989) In: Eastmond GC, Ledwith A, Russo S. Sigwalt P (eds) Comprehensive polymer science, vol 6. Pergamon, New York, p 597 22. Huang SJ (1985) In: Encyclopedia of polymer science and engineering, 2nd edn vol 2. John Wiley, New York, p 221 23. Potts JE (1984) In: Encyclopedia of chemical technology, Suppol Vol. Wiley Interscience, New York, p 626 24.
CH,0. \ CH2O • CH-CH,Z I a 52 J. Heller However, because the addition of an alcohol to a ketene acetal is an acidcatalyzed reaction, formation of polymers by the addition of diols to this diketene acetal is greatly complicated by the extreme susceptibility of this monomer towards a competing cationic polymerization.
All of these terms can be measured, and the effectiveness of biodégradation in a given period of time can be described as follows: (1) when C r = 0 the detergent was totally biodegraded and C e = C 0 2 + C c ; (2) when C r > 0, incomplete biodégradation has occurred; and (3) when C r = C e no biodégradation has occurred If C r > 0, the fate of the incompletely biodegraded residue is important, especially the toxicity of the residue. For an anaerobic process, the equivalent analysis would be described by the following equation: C e = C 0 2 + CH 4 + Cc + C r Acknowledgement.
Biopolymers / 1